tert-Butyl 6-amino-5-cyano-2-(2-methoxyethyl)nicotinate

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tert-Butyl 6-amino-5-cyano-2-(2-meth­oxy­eth­yl)nicotinate

The title compound, C(14)H(19)N(3)O(3), was synthesized by the reaction of 3-meth-oxy-propionitrile, tert-butyl bromo-acetate and eth-oxy-methyl-enemalononitrile. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into chains propagating along the b axis.

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5-tert-Butyl-2-[5-(5-tert-butyl-1,3-benzoxazol-2-yl)-2-thien­yl]-1,3-benzoxazole

The title compound, C(26)H(26)N(2)O(2)S, was prepared by the reaction of thio-phene-2,5-dicarboxylic acid and 2-amino-4-tert-butyl-phenol. One of the tert-butyl groups is disordered over two conformations, with occupancies of 0.539 (1) and 0.461 (2). The two 1,3-benzoxazole rings are almost planar, with dihedral angles of 0.83 (18) and 1.64 (17)° between the five- and six-membered rings. The th...

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2-Amino-4-tert-butyl-5-(4-chloro­benz­yl)thia­zole

In the title compound, C(14)H(17)ClN(2)S, the dihedral angle between the planes of the thia-zole and chloro-phenyl rings is 88.86 (3)°. In the crystal, inversion dimers occur, linked by pairs of N-H⋯N hydrogen bonds.

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6-[(5-tert-Butyl-2-hydroxy­anilino)methyl­ene]cyclo­hexa-2,4-dienone

In the title compound, C(17)H(19)NO(2), the dihedral angle between the two aromatic rings is 26.02 (5)°. One phenol O atom is deprotonated and the N atom of the azomethine unit carries the H atom, forming an intra-molecular hydrogen bond. The packing is stabilized by an O-H⋯O hydrogen bond.

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2-tert-Butyl-6-(cyclo­hexyl­imino­meth­yl)-4-meth­oxy­phenol

The asymmetric unit of the title Schiff base compound, C(18)H(27)NO(2), contains two independent mol-ecules in which the C=N bond lengths are 1.278 (2) and 1.280 (2) Å and the cyclo-hexane rings adopt chair conformations. Intra-molecular O-H⋯N hydrogen bonding between hy-droxy and imine groups and weak C-H⋯O hydrogen bonds help to stabilize the mol-ecular structure.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812014328